Metabolic Traits: C(Young leaf)CG(Young leaf)EC(Young leaf)ECG(Young leaf)EGC(Young leaf)EGCG(Young leaf)GA(Young leaf)GC(Young leaf)GCG(Young leaf)C(Third leaf)CG(Third leaf)EC(Third leaf)ECG(Third leaf)EGC(Third leaf)EGCG(Third leaf)GA(Third leaf)GC(Third leaf)GCG(Third leaf)C(Mature leaf)CG(Mature leaf)EC(Mature leaf)ECG(Mature leaf)EGC(Mature leaf)EGCG(Mature leaf)GA(Mature leaf)GC(Mature leaf)GCG(Mature leaf)1.01_365.1044m/z(POS mode; sucrose)1.31_175.1063m/z(POS mode; theanine isomer)1.40_174.0991n(POS mode; theanine)1.52_308.0900m/z(POS mode; glutathione)1.80_224.1266m/z(POS mode; unknown)1.92_303.0123m/z(POS mode; ellagic acid isomer)2.06_167.0549m/z(POS mode; ribonic acid)2.47_593.1288m/z(POS mode; procyanidin A4)2.81_167.0547m/z(POS mode; arabinonic acid)2.89_344.0732n(POS mode; theogallin)3.33_611.1388m/z(POS mode; prodelphinidin B isomer 1)3.48_611.1392m/z(POS mode; prodelphinidin B isomer 3)3.77_181.0707m/z(POS mode; theobromine)3.82_307.0808m/z(POS mode; gallocatechin)3.98_230.1384m/z(POS mode; unknown)4.11_595.1439m/z(POS mode; EC-GC dimer isomer 1)4.11_611.1391m/z(POS mode; prodelphinidin B isomer 2)4.14_617.0771m/z(POS mode; phyllanemblinin A?)4.34_595.1442m/z(POS mode; EC-GC dimer isomer 2)4.38_763.1504m/z(POS mode; theasinensin B isomer 1)4.42_595.1442m/z(POS mode; EC-GC dimer isomer 3)4.57_635.0879m/z(POS mode; strictinin)4.58_617.0771m/z(POS mode; an unknown ellagitannin)4.80_595.1443m/z(POS mode; EC-GC dimer isomer 4)4.91_306.0732n(POS mode; epigallocatechin)4.92_595.1438m/z(POS mode; EC-GC dimer isomer 5)4.96_763.1502m/z(POS mode; galloylprodelphinidin dimer isomer 3)5.00_314.0628n(POS mode; unknown)5.11_579.1493m/z(POS mode; procyanidin B3)5.12_785.1316m/z(POS mode; galloylprodelphinidin dimer isomer 1)5.13_428.0395n(POS mode; unknown)5.14_449.1067m/z(POS mode; kaempferol hexose)5.23_1067.2080m/z(POS mode; taraninin (aka. EGC-EGCG-EGC))5.26_225.0972m/z(POS mode; theacrine)5.33_291.0852m/z(POS mode; catechin)5.35_185.0428m/z(POS mode; methylgallate)5.48_441.0806m/z(POS mode; kaempferol 3-arabinoside)5.49_439.1560m/z(POS mode; phenylethyl primeveroside isomer 1)5.51_377.0830m/z(POS mode; chlorogenic acid)5.56_195.0883m/z(POS mode; caffeine)5.67_578.1422n(POS mode; procyanidin B2)5.77_763.1501m/z(POS mode; galloylprodelphinidin dimer isomer 2)5.83_747.1552m/z(POS mode; EC-EGCG dimer)5.85_914.1535n(POS mode; theasinensin A )5.87_583.1654m/z(POS mode; norrubrofusarin 6-β-gentiobioside)5.94_373.1819m/z(POS mode; menthanetriol glucoside)5.98_867.2124m/z(POS mode; procyanidin trimer )6.03_746.1481n(POS mode; (E)GC-(E)CG dimer isomer 1)6.09_793.1609m/z(POS mode; baeckein C isomer?)6.11_467.0812m/z(POS mode; galloylnorbergenin )6.22_595.1652m/z(POS mode; C-diglucosylapigenin)6.24_290.0781n(POS mode; epicatechin)6.29_330.2024m/z(POS mode; unknown)6.33_458.0846n(POS mode; epigallocatechin gallate)6.38_361.0879m/z(POS mode; 5-p-coumaroylquinic acid)6.44_731.1602m/z(POS mode; (E)C-(E)CG dimer)6.48_867.2125m/z(POS mode; procyanidin trimer isomer 2)6.51_1051.2137m/z(POS mode; unknown)6.58_553.1542m/z(POS mode; gentioside?)6.63_659.0851m/z(POS mode; trigalloylglucose isomer 2)6.65_633.1083m/z(POS mode; 8-C-ascorbylepigallocatechin 3-gallate)6.68_481.0733m/z(POS mode; 3-galloylgallocatechin)6.70_898.1585n(POS mode; ECG-EGCG dimer isomer 1)6.78_730.1530n(POS mode; galloylprocyanidin dimer isomer 1)6.80_899.1660m/z(POS mode; theasinensin F)6.81_593.1282m/z(POS mode; catechin-(2'→2')-taxifolin)6.89_565.1547m/z(POS mode; apigenin 6-C-glucoside 8-C-arabinoside)6.95_903.2769m/z(POS mode; kaempferol deoxyhexose-hexose-deoxyhexose-hexose isomer 1)6.98_1035.2183m/z(POS mode; unknown, isomer of 7.43_1035.2182m/z)7.00_760.1277n(POS mode; prodelphinidin A2 3'-gallate )7.01_480.0896n(POS mode; myricetin 3-galactoside)7.03_442.2684m/z(POS mode; unknown)7.06_439.1563m/z(POS mode; phenylethyl primeveroside isomer 2)7.10_480.0897n(POS mode; myricetin 3'-glucoside)7.17_903.2771m/z(POS mode; kaempferol deoxyhexose-hexose-deoxyhexose-hexose isomer 2)7.19_275.0901m/z(POS mode; epiafzelechin)7.20_772.2061n(POS mode; quercetin 3-O-galactosyl rutinoside)7.33_715.1653m/z(POS mode; quercetin 3-(2''-p-hydroxybenzoyl-4''-p-coumaroylrhamnoside))7.34_595.1653m/z(POS mode; kaempferol deoxyhexose-hexose-deoxyhexose isomer 1)7.35_772.2062n(POS mode; quercetin 3-O-glucosyl rutinoside)7.36_915.1604m/z(POS mode; digalloylprodelphinidin dimer )7.37_741.2236m/z(POS mode; kaempferol rhamnosylrutinoside)7.38_867.2119m/z(POS mode; procyanidin trimer isomer?)7.43_1035.2182m/z(POS mode; unknown, isomer of 6.98_1035.2183m/z)7.50_883.1712m/z(POS mode; epiafzelechin 3-O-gallate-(4β→6)-epigallocatechin 3-O-gallate)7.53_619.0938m/z(POS mode; galloyl HHDP-glucose)7.58_617.1137m/z(POS mode; quercetin galloylglucoside)7.62_747.1551m/z(POS mode; (E)GC-(E)CG dimer isomer 2)7.69_610.1511n(POS mode; rutin)7.71_756.2113n(POS mode; kaempferol 3-O-galactosyl rutinoside)7.75_433.1117m/z(POS mode; vitexin)7.77_385.0213m/z(POS mode; unknown )7.80_1019.2233m/z(POS mode; EC-(4β→8)-ECG-(4β→8)-C)7.82_433.1118m/z(POS mode; isovitexin)7.84_442.0895n(POS mode; epicatechin 3-O-gallate)7.88_303.0485m/z(POS mode; tricetin )7.90_681.1663m/z(POS mode; kaempferol 3-(6G-malonylneohesperidoside))7.92_741.2235m/z(POS mode; kaempferol 3-(2''-rhamnosylrutinoside))7.99_756.2114n(POS mode; kaempferol 3-O-glucosyl rutinoside)8.00_464.0945n(POS mode; quercetin 3-O-glucoside)8.01_726.2008n(POS mode; camelliaside B)8.02_741.2236m/z(POS mode; kaempferol deoxyhexose-hexose-deoxyhexose isomer 2)8.03_913.1449m/z(POS mode; theasinensin A quinone?)8.10_744.1323n(POS mode; theacitrin 3-gallate)8.13_867.1764m/z(POS mode; epiafzelechin-epicatechin 3,3'-digallate isomer 2)8.24_899.1654m/z(POS mode; ECG-EGCG dimer )8.26_740.2164n(POS mode; kaempferol 3-neohesperidoside-7-rhamnoside)8.27_799.2294m/z(POS mode; kaempferol 3-O-[2"-(4'"-acetyl-rhamnosyl)-6"-glucosyl] glucoside isomer 2)8.34_625.1548m/z(POS mode; isorhamnetin coumaroylhexose)8.41_551.1030m/z(POS mode; quercetin malonyl hexose)8.42_594.1530n(POS mode; kaempferol 3-O-rutinoside)8.44_1047.1819m/z(POS mode; unknown)8.49_471.0890m/z(POS mode; kaempferol 3-O-galactoside)8.50_899.1662m/z(POS mode; ECG-EGCG dimer isomer 3)8.52_601.1186m/z(POS mode; astragalin gallate)8.70_798.2219n(POS mode; kaempferol 3-O-[2"-(4'"-acetyl-rhamnosyl)-6"-glucosyl] glucoside isomer 1)8.72_783.2342m/z(POS mode; kaempferol deoxyhexose-acetylhexose deoxyhexose isomer 1)8.76_448.0997n(POS mode; kaempferol 3-O-glucoside)8.84_731.1605m/z(POS mode; galloylprocyanidin dimer isomer 2)8.88_727.1293m/z(POS mode; unknown)8.89_456.1047n(POS mode; epicatechin 3-(3-O-methylgallate))8.92_799.2289m/z(POS mode; kaempferol-3-O-[4""-O-acetyl-a-L-rhamnopyranosyl-(1→6)]-[β-D-glucopyranosyl-(1→2)]-β-glucopyranoside)8.94_426.0946n(POS mode; epiafzelechin 3-gallate)9.07_783.2343m/z(POS mode; kaempferol deoxyhexose-acetylhexose deoxyhexose isomer 2)9.09_759.1553m/z(POS mode; unknown)9.11_897.1503m/z(POS mode; unknown)9.31_535.1081m/z(POS mode; malonylastragalin)9.37_883.1708m/z(POS mode; digalloylprocyanidin dimer)9.71_1081.3025m/z(POS mode; quercetin 3-triglucoside-7-rhamnoside-p-coumaroyl isomer 1)9.92_1064.3006n(POS mode; capilliposide I isomer 1)10.03_1050.2852n(POS mode; camelliquercetiside A isomer 1)10.08_1035.2970m/z(POS mode; quercetin 3-O-(2G-p-coumaroyl-3G-O-β-L-arabinosyl-3R-O-β-D-rhamnosylrutinoside))10.19_1048.3057n(POS mode; capilliposide II isomer 1)10.21_1065.3082m/z(POS mode; kaempferol 3-O-β-D-glucopyranosyl(1→4)-[α-L-rhamnopyranosyl(1→6)]-β-D-glucopyranoside-7-O-[2-O-(E)-p-coumaroyl]-β-D-glucopyranoside)10.24_902.2476n(POS mode; sarmenoside II)10.34_1051.2922m/z(POS mode; camelliquercetiside A isomer 2)10.41_1033.3179m/z(POS mode; kaempferol 3-(p-coumaroyl-rhamnosyl)rutinoside-7-rhamnoside isomer 1)10.49_1034.2903n(POS mode; camellikaempferoside C isomer 1)10.52_1005.2865m/z(POS mode; unknown kaempferol glycoside )10.56_886.2527n(POS mode; camellikaempferoside B)10.57_1065.3083m/z(POS mode; capilliposide I isomer 3)10.68_925.2364m/z(POS mode; kaempferol 3-neohesperidoside-7-(2"-p-coumaroylglucoside) isomer 1)10.71_1019.3019m/z(POS mode; kaempferol-3-O-{[β-D-xylopyranosyl(1→3)-α-L-rhamnopyranosyl(1→6)][α-L-rhamnopyranosyl(1→2)]}-β-D-3-trans-p-coumaroylgalactopyranoside)10.74_1035.2975m/z(POS mode; camellikaempferoside C isomer 2)10.86_1049.3128m/z(POS mode; capilliposide II isomer 2)10.91_872.2373n(POS mode; camellikaempferoside A isomer 1)11.00_594.1373n(POS mode; kaempferol coumaroyl hexose)11.14_873.2445m/z(POS mode; camellikaempferoside A isomer 2)11.19_471.2191m/z(POS mode; linalool primeveroside isomer 1)11.23_887.2601m/z(POS mode; kaempferol 3-(4''-(E)-p-coumaroylrobinobioside)-7-rhamnoside isomer 2)11.48_471.2191m/z(POS mode; linalool primeveroside isomer 2)12.33_353.1560m/z(POS mode; an unknown monoterpene glycoside?)12.34_337.1971m/z(POS mode; an unknown alkaloid?)12.43_467.1327m/z(POS mode; an unknown flavonolignan?)13.40_451.1377m/z(POS mode; unknown)14.30_855.4520m/z(POS mode; unknown)14.89_307.0974m/z(POS mode; unknown)14.93_227.1871n(POS mode; an unknown alkaloid?)15.07_278.0849n(POS mode; unknown)15.31_292.1027n(POS mode; unknown)15.33_225.1947m/z(POS mode; an unknown alkaloid?)15.43_1197.5669m/z(POS mode; unknown, isomer of 15.65_1197.5669m/z)15.57_1139.5606m/z(POS mode; unknown)15.65_1197.5669m/z(POS mode; unknown, isomer of 15.43_1197.5669m/z)15.66_613.3728m/z(POS mode; yemuoside I isomer 2)15.91_391.2080m/z(POS mode; unknown)15.93_993.5010m/z(POS mode; saponin Iac)16.32_449.1480m/z(POS mode; unknown)16.34_845.4668m/z(POS mode; unknown)16.36_1181.5707m/z(POS mode; eupteleasaponin IV isomer 2)16.37_683.4147m/z(POS mode; an unknown terpenoid, isomer of 16.69_683.4145m/z)16.55_779.4358m/z(POS mode; unknown)16.63_939.4726m/z(POS mode; unknown)16.69_683.4145m/z(POS mode; an unknown terpenoid, isomer of 16.37_683.4147m/z)16.80_1155.5335m/z(POS mode; tragopogonsaponin E)16.89_731.4146m/z(POS mode; unknown)1.01_342.1163n(NEG mode; sucrose)1.30_173.0931m/z(NEG mode; theanine isomer)1.40_173.0932m/z(NEG mode; theanine)1.52_306.0763m/z(NEG mode; glutathione)1.71_191.0193m/z(NEG mode; citric acid)1.71_203.0195m/z(NEG mode; oxaloglutarate?)1.93_481.0621m/z(NEG mode; hexahydroxydiphenoyl-glucose)1.95_295.1033m/z(NEG mode; unknown, may be a disaccharide, isomer of 2.23_295.1033m/z)2.13_611.1444m/z(NEG mode; oxidized glutathione)2.23_295.1033m/z(NEG mode; unknown, may be a disaccharide, isomer of 1.95_295.1033m/z)2.42_331.0668m/z(NEG mode; monogalloylglucose isomer 1)2.47_609.1245m/z(NEG mode; theasinensin C)2.64_331.0668m/z(NEG mode; monogalloylglucose isomer 2)2.89_344.0743n(NEG mode; theogallin)3.14_208.0612m/z(NEG mode; unknown)3.19_343.0668m/z(NEG mode; galloylquinic acid)3.34_609.1247m/z(NEG mode; prodelphinidin B isomer 1)3.39_467.1191m/z(NEG mode; gallocatechin hexoside )3.48_609.1246m/z(NEG mode; prodelphinidin B isomer 3)3.64_345.0824m/z(NEG mode; methyl galloylglucose)3.83_306.0740n(NEG mode; gallocatechin)4.09_473.0724m/z(NEG mode; chicoric acid isomer?)4.11_593.1297m/z(NEG mode; EC-GC dimer isomer 1)4.12_609.1246m/z(NEG mode; prodelphinidin B isomer 2)4.15_317.0398n(NEG mode; strictinin isomer 1)4.22_357.0824m/z(NEG mode; dihydrocaffeic acid 3-O-glucuronide)4.34_353.0874m/z(NEG mode; caffeoylquinic acid)4.35_593.1298m/z(NEG mode; EC-GC dimer isomer 2)4.38_761.1356m/z(NEG mode; theasinensin B isomer 1)4.42_483.0777m/z(NEG mode; digalloylglucose isomer 2)4.44_593.1297m/z(NEG mode; EC-GC dimer isomer 3 )4.58_317.0398n(NEG mode; strictinin isomer 2)4.75_483.0776m/z(NEG mode; digalloylglucose isomer 3)4.79_577.1348m/z(NEG mode; procyanidin B1)4.80_593.1297m/z(NEG mode; EC-GC dimer isomer 4)4.83_759.1198m/z(NEG mode; theacitrin A)4.91_611.1407m/z(NEG mode; epigallocatechin)4.93_593.1293m/z(NEG mode; EC-GC dimer isomer 5)4.96_761.1354m/z(NEG mode; galloylprodelphinidin dimer isomer 3)5.01_242.0423n(NEG mode; digalloylglucose isomer 1)5.11_577.1348m/z(NEG mode; procyanidin B3)5.14_381.0712n(NEG mode; galloylprodelphinidin dimer isomer 1)5.15_337.0926m/z(NEG mode; 3-p-coumaroylquinic acid)5.21_639.1350m/z(NEG mode; unknown)5.23_533.1003n(NEG mode; unknown trimeric proanthocyanidin isomer 1)5.26_865.1979m/z(NEG mode; procyanidin trimer isomer?)5.33_611.1613m/z(NEG mode; carthamidin diglucoside isomer 1)5.34_290.0791n(NEG mode; catechin)5.36_183.0298m/z(NEG mode; methylgallate)5.48_457.0773m/z(NEG mode; gallocatechin 3'-O-gallate)5.51_354.0948n(NEG mode; chlorogenic acid)5.68_577.1350m/z(NEG mode; procyanidin B2)5.71_595.1661m/z(NEG mode; isorubrofusarin gentiobioside)5.75_533.1006n(NEG mode; unknown trimeric proanthocyanidin isomer 2)5.77_761.1352m/z(NEG mode; galloylprodelphinidin dimer isomer 2)5.78_593.1285m/z(NEG mode; EC-GC dimer isomer 6)5.85_457.0766n(NEG mode; theasinensin A)5.87_581.1508m/z(NEG mode; norrubrofusarin 6-β-gentiobioside)5.95_350.1936n(NEG mode; menthanetriol glucoside)5.99_865.1978m/z(NEG mode; procyanidin trimer isomer 1)6.03_745.1406m/z(NEG mode; (E)GC-(E)CG dimer isomer 1)6.11_337.0926m/z(NEG mode; 4-p-coumaroylquinic acid)6.12_635.0883m/z(NEG mode; trigalloylglucose isomer 1)6.23_593.1501m/z(NEG mode; C-diglucosylapigenin)6.25_290.0794n(NEG mode; epicatechin)6.29_525.1026n(NEG mode; a possible galloylated trimeric proanthocyanidin, isomer of 6.51_525.1026n)6.34_458.0851n(NEG mode; epigallocatechin gallate)6.38_795.1775m/z(NEG mode; unknown)6.39_337.0927m/z(NEG mode; 5-p-coumaroylquinic acid)6.45_393.0451n(NEG mode; digalloyl-hexahydroxydiphenoyl-glucose)6.48_865.1975m/z(NEG mode; procyanidin trimer isomer 2)6.51_525.1026n(NEG mode; a possible galloylated trimeric proanthocyanidin)6.54_449.1083m/z(NEG mode; maesopsin 6-glucoside)6.57_551.1402m/z(NEG mode; gentioside?)6.60_491.1402m/z(NEG mode; unknown)6.63_318.0476n(NEG mode; trigalloylglucose isomer 2)6.65_631.0934m/z(NEG mode; 8-C-ascorbylepigallocatechin 3-gallate)6.67_761.1350m/z(NEG mode; theasinensin B isomer 2)6.68_915.1622m/z(NEG mode; 3-galloylgallocatechin)6.70_593.1108n(NEG mode; unknown, isomer of 7.03_593.1107n)6.71_897.1512m/z(NEG mode; ECG-EGCG dimer isomer 1)6.78_729.1455m/z(NEG mode; galloylprocyanidin dimer isomer 1)6.80_449.0791n(NEG mode; theasinensin F)6.85_609.1450m/z(NEG mode; quercetin rutinoside, isomer of rutin)6.90_563.1401m/z(NEG mode; apigenin 6-C-glucoside 8-C-arabinoside)6.92_625.1404m/z(NEG mode; myricetin 3-neohesperidoside or 3-robinobioside)6.93_901.2611m/z(NEG mode; kaempferol hexose-deoxyhexose-deoxyhexose-hexose isomer 1)6.95_539.2130m/z(NEG mode; unknown)6.98_538.2046n(NEG mode; unknown)6.99_1033.2033m/z(NEG mode; unknown, isomer of 7.44_517.1053n)7.00_759.1242m/z(NEG mode; unknown)7.01_479.0825m/z(NEG mode; myricetin 3-galactoside)7.03_593.1107n(NEG mode; unknown, isomer of 6.70_593.1108n)7.06_416.1674n(NEG mode; phenylethyl primeveroside isomer 2)7.10_479.0826m/z(NEG mode; myricetin 3'-glucoside)7.17_901.2608m/z(NEG mode; kaempferol hexose-deoxyhexose-deoxyhexose-hexose isomer 2)7.20_273.0765m/z(NEG mode; epiafzelechin)7.20_771.1983m/z(NEG mode; quercetin 3-O-galactosyl rutinoside)7.32_741.1876m/z(NEG mode; quercetin hexose deoxyhexose-pentose)7.33_593.1498m/z(NEG mode; kaempferol deoxyhexose-hexose-deoxyhexose isomer 1)7.34_713.1504m/z(NEG mode; fisetinidol-(4α→8)-catechin-3-O-gallate)7.35_771.1985m/z(NEG mode; quercetin 3-O-glucosyl rutinoside)7.39_865.1974m/z(NEG mode; procyanidin trimer isomer?)7.44_517.1053n(NEG mode; unknown, isomer of 6.99_1033.2033m/z)7.49_521.2020m/z(NEG mode; isolariciresinol glucoside)7.51_881.1563m/z(NEG mode; epiafzelechin 3-O-gallate-(4β→6)-epigallocatechin 3-O-gallate)7.55_394.0530n(NEG mode; tetragalloyl glucose)7.59_615.0988m/z(NEG mode; quercetin galloylglucoside)7.62_745.1404m/z(NEG mode; (E)GC-(E)CG dimer isomer 2)7.64_477.0670m/z(NEG mode; unknown)7.67_577.1556m/z(NEG mode; vitexin rhamnoside isomer 2)7.69_609.1438m/z(NEG mode; rutin)7.71_755.2034m/z(NEG mode; kaempferol 3-O-galactosyl rutinoside)7.72_823.1907m/z(NEG mode; kaempferol 3-(3",6"-diacetyl-2",4"-di-p-coumaroylrhamnoside))7.75_725.1929m/z(NEG mode; kaempferol deoxyhexose-pentose-hexose )7.80_509.1080n(NEG mode; EC-(4β→8)-ECG-(4β→8)-C)7.82_431.0976m/z(NEG mode; isovitexin)7.82_745.1401m/z(NEG mode; (E)GC-(E)CG dimer isomer 3)7.85_442.0901n(NEG mode; epicatechin 3-O-gallate)7.92_609.0940m/z(NEG mode; epigallocatechin digallate isomer 2)7.94_597.1820m/z(NEG mode; catechin rutinoside?)7.99_755.2038m/z(NEG mode; kaempferol 3-O-glucosyl rutinoside)8.00_464.0948n(NEG mode; quercetin 3-O-glucoside)8.02_739.2082m/z(NEG mode; kaempferol deoxyhexose-hexose-deoxyhexose isomer 2)8.05_599.1036m/z(NEG mode; (iso)orientin gallate ?)8.10_743.1248m/z(NEG mode; theacitrin 3-gallate)8.14_433.0841n(NEG mode; epiafzelechin-epicatechin 3,3'-digallate isomer 2)8.24_449.0791n(NEG mode; ECG-EGCG dimer isomer 2)8.26_739.2086m/z(NEG mode; kaempferol 3-neohesperidoside-7-rhamnoside)8.27_797.2135m/z(NEG mode; kaempferol 3-O-[2"-(4'"-acetyl-rhamnosyl)-6"-glucosyl] glucoside isomer 2)8.32_609.1455m/z(NEG mode; quercetin hexose deoxyhexose)8.34_467.0979m/z(NEG mode; epigallocatechin 3-O-caffeate)8.42_593.1505m/z(NEG mode; kaempferol 3-O-rutinoside)8.50_447.0927m/z(NEG mode; kaempferol 3-O-galactoside)8.52_599.1037m/z(NEG mode; astragalin gallate)8.54_464.2242n(NEG mode; linalool oxide primeveroside)8.70_797.2141m/z(NEG mode; kaempferol 3-O-[2"-(4'"-acetyl-rhamnosyl)-6"-glucosyl] glucoside isomer 1)8.71_781.2189m/z(NEG mode; kaempferol deoxyhexose-acetylhexose deoxyhexose isomer 1)8.77_448.1001n(NEG mode; kaempferol 3-O-glucoside)8.81_849.1666m/z(NEG mode; unknown)8.84_729.1456m/z(NEG mode; galloylprocyanidin dimer isomer 2)8.94_426.0950n(NEG mode; epiafzelechin 3-gallate)8.99_441.0815n(NEG mode; epicatechin-(4α→8)-epicatechin 3,3'-digallate)9.00_635.1609m/z(NEG mode; kaempferol acetylhexose deoxyhexose isomer 1)9.07_781.2191m/z(NEG mode; kaempferol deoxyhexose-acetylhexose deoxyhexose isomer 2)9.31_489.1033m/z(NEG mode; kaempferol 3-(6-acetylgalactoside))9.33_635.1615m/z(NEG mode; kaempferol acetylhexose deoxyhexose isomer 2)9.37_441.0818n(NEG mode; digalloylprocyanidin dimer)9.57_540.1475n(NEG mode; quercetin 3-triglucoside-7-rhamnoside-p-coumaroyl isomer 1)9.59_635.1608m/z(NEG mode; kaempferol acetylhexose deoxyhexose isomer 3)9.68_1049.2769m/z(NEG mode; quercetin 3-O-(2G-p-coumaroyl-3G-O-β-L-arabinosyl-3R-O-β-D-glucosylrutinoside) isomer)9.70_532.1501n(NEG mode; capilliposide I isomer 4)9.71_540.1476n(NEG mode; quercetin 3-triglucoside-7-rhamnoside-p-coumaroyl isomer 2)9.76_431.0978m/z(NEG mode; kaempferol 3-rhamnoside)9.85_1149.5313m/z(NEG mode; an unknown triterpenoid saponin)9.86_540.1477n(NEG mode; quercetin 3-triglucoside-7-rhamnoside-p-coumaroyl isomer 3)9.92_532.1501n(NEG mode; capilliposide I isomer 1)10.02_590.1736n(NEG mode; kaempferol 3-O-(β-D-xylopyranosyl(1→3)-(4-O-E-p-coumaroyl-α-L-rhamnopyranosyl(1→2))[β-D-glucopyranosyl(1→6)]-β-D-galactopyranoside)-7-O-(α-L-rhamnopyranoside))10.03_525.1431n(NEG mode; quercetin 3-O-(2G-p-coumaroyl-3G-O-β-L-arabinosyl-3R-O-β-D-glucosylrutinoside))10.06_1019.2668m/z(NEG mode; unknown)10.07_517.6463n(NEG mode; quercetin 3-O-(2G-p-coumaroyl-3G-O-β-L-arabinosyl-3R-O-β-D-rhamnosylrutinoside))10.09_433.0841n(NEG mode; epiafzelechin-epicatechin 3,3'-digallate)10.11_917.2348m/z(NEG mode; capilliposide I isomer 2)10.19_524.1525n(NEG mode; capilliposide II isomer 1)10.21_532.1501n(NEG mode; kaempferol 3-O-β-D-glucopyranosyl(1→4)-[α-L-rhamnopyranosyl(1→6)]-β-D-glucopyranoside-7-O-[2-O-(E)-p-coumaroyl]-β-D-glucopyranoside)10.22_459.1209n(NEG mode; quercetin 3-(6'''-p-coumaroylglucosyl)(1→2)-rhamnoside 7-glucoside isomer 1)10.24_451.1235n(NEG mode; sarmenoside II)10.31_609.1247m/z(NEG mode; quercetin 3-(3-p-coumaroylglucoside)?)10.34_1049.2769m/z(NEG mode; camelliquercetiside A)10.41_516.1552n(NEG mode; kaempferol 3-(p-coumaroyl-rhamnosyl)rutinoside-7-rhamnoside isomer 1)10.48_517.1448n(NEG mode; camellikaempferoside C isomer 1)10.53_502.1395n(NEG mode; unknown kaempferol glycoside )10.55_443.1260n(NEG mode; kaempferol 3-(4''-(E)-p-coumaroylrobinobioside)-7-rhamnoside isomer 1)10.58_532.1501n(NEG mode; capilliposide I isomer 3)10.61_1133.5362m/z(NEG mode; echinocystic acid 3-O-[β-D-galactopyranosyl(1→2)]-[β-D-glucopyranosyl(1→2)-β-D-galactopyranosyl(1→3)]-β-D-glucuronopyranoside isomer 1)10.65_887.2246m/z(NEG mode; camelliquercetiside C)10.67_901.2399m/z(NEG mode; kaempferol 3-neohesperidoside-7-(2"-p-coumaroylglucoside) isomer 1)10.70_509.1471n(NEG mode; unknown)10.74_517.1448n(NEG mode; camellikaempferoside C isomer 2)10.76_483.1294m/z(NEG mode; di-p-cis-coumaroylquinic acid isomer 1)10.80_739.1875m/z(NEG mode; kaempferol coumaroylrutinoside isomer 1)10.81_478.2406n(NEG mode; unknown monoterpene glycoside)10.81_917.2350m/z(NEG mode; quercetin 3-(6'''-p-coumaroylglucosyl)(1→2)-rhamnoside 7-glucoside isomer 2)10.86_524.1526n(NEG mode; capilliposide II isomer 2)10.88_1017.2868m/z(NEG mode; 4',5,7-Trihydroxy-3-[2-O-α-L-rhamnopyranosyl-3 (or 4)-O-(4-hydroxy-trans-cinnamoyl)-6-O-(3-O-β-D-xylopyranosyl-alpha-L-rhamnopyranosyl)-β-D-galactopyranosyloxy]flavone)10.89_901.2400m/z(NEG mode; kaempferol 3-neohesperidoside-7-(2"-p-coumaroylglucoside) isomer 2)10.90_436.1180n(NEG mode; camellikaempferoside A isomer 1)11.00_593.1297m/z(NEG mode; kaempferol coumaroyl hexose )11.02_755.1824m/z(NEG mode; 6"-(4-hydroxycinnamoyl)astragalin 4'-glucoside)11.07_516.1550n(NEG mode; kaempferol 3-(p-coumaroyl-rhamnosyl)rutinoside-7-rhamnoside isomer 2)11.08_901.2400m/z(NEG mode; kaempferol 3-neohesperidoside-7-(2"-p-coumaroylglucoside) isomer 3)11.13_871.2298m/z(NEG mode; camellikaempferoside A isomer 2)11.18_1131.5571m/z(NEG mode; calendulaglycoside A 6'-methyl ester)11.20_448.2300n(NEG mode; linalool primeveroside isomer 1)11.23_443.1260n(NEG mode; kaempferol 3-(4''-(E)-p-coumaroylrobinobioside)-7-rhamnoside isomer 2)11.26_739.1875m/z(NEG mode; kaempferol coumaroylrutinoside isomer 2)11.28_901.2399m/z(NEG mode; kaempferol 3-neohesperidoside-7-(2"-p-coumaroylglucoside) isomer 4)11.33_1189.5616m/z(NEG mode; theasaponin A1)11.36_1133.5360m/z(NEG mode; echinocystic acid 3-O-[β-D-galactopyranosyl(1→2)]-[β-D-glucopyranosyl(1→2)-β-D-galactopyranosyl(1→3)]-β-D-glucuronopyranoside isomer 2)11.38_1175.5458m/z(NEG mode; herniariasaponin isomer)11.48_448.2301n(NEG mode; linalool primeveroside isomer 2)11.57_985.5000m/z(NEG mode; an unknown triterpenoid saponin)11.73_1043.5052m/z(NEG mode; namonin E?)12.44_483.1293m/z(NEG mode; di-p-cis-coumaroylquinic acid isomer 2)12.99_1085.5152m/z(NEG mode; camellioside C isomer 1)13.14_467.1913m/z(NEG mode; paucin)13.20_881.4519m/z(NEG mode; an unknown steroidal saponin)13.40_467.1343m/z(NEG mode; unknown)13.67_1089.5469m/z(NEG mode; saponin 61)13.70_1075.5315m/z(NEG mode; an unknown triterpenoid saponin)13.77_1117.5415m/z(NEG mode; camellidin III)14.04_739.1663m/z(NEG mode; 2'',4''-Bis-O-(4-hydroxycinnamoyl)astragalin)14.37_1088.5391n(NEG mode; sanchakasaponin A)14.42_1059.5365m/z(NEG mode; medicoside I isomer)14.47_1085.5159m/z(NEG mode; camellioside C isomer 2)14.50_1147.5363m/z(NEG mode; unknown)14.75_927.4948m/z(NEG mode; saponin I)14.77_1173.5669m/z(NEG mode; yemuoside I isomer 1)14.83_1159.5514m/z(NEG mode; an unknown triterpenoid saponin)14.94_1057.5213m/z(NEG mode; araloside B isomer)14.97_1089.5396m/z(NEG mode; unknown)15.12_1027.5106m/z(NEG mode; TR-Saponin C)15.24_1187.5466m/z(NEG mode; theasaponin E6)15.42_1173.5674m/z(NEG mode; yemuoside I isomer 3)15.56_1175.5821m/z(NEG mode; asterlingulatoside D)15.57_1116.5696n(NEG mode; xanifolia-Y0 isomer)15.62_1101.5465m/z(NEG mode; an unknown triterpenoid saponin)15.65_1173.5669m/z(NEG mode; yemuoside I isomer 2)15.84_1195.5503m/z(NEG mode; unknown)15.92_969.5050m/z(NEG mode; saponin Iac)15.97_1145.5512m/z(NEG mode; acutanguloside E)16.06_837.4626m/z(NEG mode; an unknown triterpenoid saponin)16.13_1157.5718m/z(NEG mode; eupteleasaponin IV isomer 1)16.19_1147.5300m/z(NEG mode; unknown, isomer of 14.50_1147.5363m/z)16.21_1083.5361m/z(NEG mode; oleiferasaponin C5)16.25_1069.5205m/z(NEG mode; camellioside H)16.26_1187.5814m/z(NEG mode; camelliasaponin A1/A2)16.31_1015.4887m/z(NEG mode; tencissoside C isomer 1)16.34_1171.5833m/z(NEG mode; 3-O-(4-O-[3-hydroxy-3-methylglutaryl])-α-L-arabinopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)-[α-D-glucopyranosyl-(1→4)]-α-L-arabinopyranosyloleanolic acid )16.35_1147.5301m/z(NEG mode; unknown, isomer of 14.50_1147.5363m/z)16.36_1157.5720m/z(NEG mode; eupteleasaponin IV isomer 2)16.41_1125.5460m/z(NEG mode; xanifolia-Y3 isomer 1)16.41_1189.5400m/z(NEG mode; unknown)16.46_1183.5494m/z(NEG mode; unknown)16.54_1057.4992m/z(NEG mode; unknown)16.64_1147.5298m/z(NEG mode; unknown, isomer of 14.50_1147.5363m/z)16.69_1125.5461m/z(NEG mode; xanifolia-Y3 isomer 2)16.80_1131.5352m/z(NEG mode; tragopogonsaponin E)16.81_1015.4888m/z(NEG mode; tencissoside C isomer 2)16.86_993.5047m/z(NEG mode; rogachaponin)16.91_1159.5298m/z(NEG mode; unknown)16.96_1173.5451m/z(NEG mode; unknown)16.98_999.4939m/z(NEG mode; unknown)

Note: The metabolic traits are from the article Genome assembly of wild tea tree DASZ reveals pedigree and selection history of tea varieties and Metabolite signatures of diverse Camellia sinensis tea populations.

Variation ID: